A transformative approach is required to meet the demand of economically viable solar cell technology. By making use of recent advances in semiconductor nanocrystal research, we have now developed a one-coat solar paint for designing quantum dot solar cells. A binder-free paste consisting of CdS, CdSe, and TiO2 semiconductor nanoparticles was prepared and applied to conducting glass surface and annealed at 473 K. The photoconversion behavior of these semiconductor film electrodes was evaluated in a photoelectrochemical cell consisting of graphene–Cu2S counter electrode and sulfide/polysulfide redox couple. Open-circuit voltage as high as 600 mV and short circuit current of 3.1 mA/cm2 were obtained with CdS/TiO2–CdSe/TiO2 electrodes. A power conversion efficiency exceeding 1% has been obtained for solar cells constructed using the simple conventional paint brush approach under ambient conditions. Whereas further improvements are necessary to develop strategies for large area, all solid state devices, this initial effort to prepare solar paint offers the advantages of simple design and economically viable next generation solar cells.
References:
Sun-Believable Solar Paint. A Transformative One-Step Approach for Designing Nanocrystalline Solar Cells
Matthew P. Genovese, Ian V. Lightcap, and Prashant V. Kamat
ACS Nano 2012 6 (1), 865-872 [Online] http://pubs.acs.org/doi/abs/10.1021/nn204381g
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